Product ID:100 7509 COLOR DEVELOPER REPLENISHER, PROCESS E-6AR, PART B
MSDS Date:07/11/2000
FSC:6750
NIIN:01-033-5154
MSDS Number: BGGFF

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

WATER

CAS: 25646-71-3

RTECS: PB0431000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

SODIUM BISULFITE

CAS: 7631-90-5

RTECS: VZ2000000

OSHA PEL NOT PROVIDED

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: VAPOR
IRRITATING. MAY BE HARMFUL IF INHALED. LIBERATES SULFUR DIOXIDE GAS
WHICH CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT. SOME
ASTHMATICS OR HYPERSENSITIVE INDIVI DUALS MAY EXPERIENCE DIFFICULT
BREATHING. EYES: CAUSES IRRITATION. VAPOR IRRITATING. SKIN: CAUSES
IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. INGESTION: HARMFUL IF
SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT.
SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): SOD IUM BISULFITE, A4;
NOT CLASSIFIABLE AS HUMAN CARCINOGEN. - NATIONAL TOXICOLOGY PROGRAM
(NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA):
NONE
Effects of Overexposure:INHALATION: VAPOR IRRITATING. LIBERATES SULFUR
DIOXIDE GAS WHICH CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT.
SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE
DIFFICULT BREATHING. EYES: CAUSES IRRITATION. VAPOR IRRITATING.
SKIN: CAUSES IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. SOME
ASTHMATICS OR SULFITE-SENSITIVE INDI VIDUALS MAY EXPERIENCE
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
SKIN: IMM EDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL
ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR
THOROUGHLY CLEAN CONTAMINATED SHOES. NGESTION: INDUCE VOMITING AS
DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE

Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION).
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID
BREATHING MIST OR VAPOR AT CONCENTRATIONS GREATER THAN THE
EXPOSURE LIMITS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY
AFTER HANDLING.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID GAS. SEE STABILITY
AND REACTIVITY SECTIO N. IF RESPIRATORS ARE USED, A PROGRAM SHOULD
BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR
1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT
PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT
ESTABLISHED.

HCC:C1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.02
pH:1.4
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT AMBER LIQUID, SULFUR DIOXIDE ODOR.
Percent Volatiles by Volume:90-95 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
BASES
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
SULFUR DIOXIDE, NITROGEN OXIDES (NOX).

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL IS SUBJECT TO
NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS
EMPTIED. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY.

Toxicological Information:DATA FOR
4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIAMINE
SESQUISULFATE MONOHYDRATE ACUTE TOXICITY DATA: ORAL LD-50 (MALE
RAT): 400 MG/KG (TARGET ORGAN EFFECTS: KIDNEY). ORAL LD-5 0
(FEMALE RAT): 246 MG/KG. DERMAL LD-50: > 1000 MG/KG (HIGHEST DOSE
TESTED). SKIN IRRITATION: SLIGHT. REPEATED SKIN APPLICATION:
MODERATE IRRITATION. SKIN SENSITIZATION: MODERATE. SKIN
SENSITIZATION (HUMAN): POSITIVE. EYE IRRITATION (UNWASHED EYES):
MODERATE. EYE IRRITATION (WASHED EYES): SLIGHT

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 10-100.
DAPHNID EC50 MG/L: 10-100. ALGAL IC50 MG/L: 10-100. ORGANICS
READILY DEGRADABLE (>70%): YES (7 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 52. BOD5
(APPROXIMATE G/L): 6. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): >100 .

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: NONE
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE